If you mean using symmetry to determine whether a molecule is polar, then here’s a good trick to use: first, identify which molecules are δ+ and δ- through electronegativity differences [higher electronegativity of elements in a bond is δ-]. Once you’ve done that and labeled each atom, the molecule is polar if you can draw a straight line seperating all δ+ and δ-. For example, while carbon dioxide has polar bonds, it is not a polar molecule, since it is structured O = C = O which turns into
δ- = δ+ = δ- and you can’t draw a line separating δ+ and δ-. Water is polar because you can draw such a line (I’ll allow you to try that for yourself).