The Student Room Group

Mc questions - a level chem

Stuck on these questions, help appreciated :smile:
Q15.
The apparatus in the figure below was set up to measure the time taken for 20.0
cm3 of sodium thiosulfate solution to react with 5.0 cm3 of hydrochloric acid in a
100 cm3 conical flask at 20 °C. The timer was started when the sodium
thiosulfate solution was added to the acid in the flask. The timer was stopped
when it was no longer possible to see the cross on the paper.
AQA Chemistry A-Level - Kinetics QP PhysicsAndMathsTutor.com
Page 19 of 22
What is likely to decrease the accuracy of the experiment?
A Rinsing the flask with acid before each new experiment.
B Stirring the solution throughout each experiment.
C Using the same piece of paper for each experiment.
D Using different measuring cylinders to measure the volumes
of acid and sodium thiosulfate.

ANSWER: A (Don't get this, I thought acid rinsing might make it more reliable? than potentially diluting the acid by rinsing with water)

Q16.
The experiment was repeated at 20 °C using a 250 cm3 conical flask.
Which statement is correct about the time taken for the cross to disappear when
using the larger conical flask?
A The time taken will not be affected by using the larger conical flask.
B The time taken will be decreased by using the larger conical flask.
C The time taken will be increased by using the larger conical flask.
D It is impossible to predict how the time taken will be affected by
using the larger conical flask.

ANSWER = C
Reply 1
Original post by mitostudent
Stuck on these questions, help appreciated :smile:
Q15.
The apparatus in the figure below was set up to measure the time taken for 20.0
cm3 of sodium thiosulfate solution to react with 5.0 cm3 of hydrochloric acid in a
100 cm3 conical flask at 20 °C. The timer was started when the sodium
thiosulfate solution was added to the acid in the flask. The timer was stopped
when it was no longer possible to see the cross on the paper.
AQA Chemistry A-Level - Kinetics QP PhysicsAndMathsTutor.com
Page 19 of 22
What is likely to decrease the accuracy of the experiment?
A Rinsing the flask with acid before each new experiment.
B Stirring the solution throughout each experiment.
C Using the same piece of paper for each experiment.
D Using different measuring cylinders to measure the volumes
of acid and sodium thiosulfate.
ANSWER: A (Don't get this, I thought acid rinsing might make it more reliable? than potentially diluting the acid by rinsing with water)
Q16.
The experiment was repeated at 20 °C using a 250 cm3 conical flask.
Which statement is correct about the time taken for the cross to disappear when
using the larger conical flask?
A The time taken will not be affected by using the larger conical flask.
B The time taken will be decreased by using the larger conical flask.
C The time taken will be increased by using the larger conical flask.
D It is impossible to predict how the time taken will be affected by
using the larger conical flask.
ANSWER = C


A makes it less reliable as you now have more acid in the flask than intended. Meaning the volume is wrong hence the number of moles.
Reply 2
You have confused titration and the cross clock, 2 different experiments that's all
Reply 3
Original post by mitostudent
Stuck on these questions, help appreciated :smile:
Q15.
The apparatus in the figure below was set up to measure the time taken for 20.0
cm3 of sodium thiosulfate solution to react with 5.0 cm3 of hydrochloric acid in a
100 cm3 conical flask at 20 °C. The timer was started when the sodium
thiosulfate solution was added to the acid in the flask. The timer was stopped
when it was no longer possible to see the cross on the paper.
AQA Chemistry A-Level - Kinetics QP PhysicsAndMathsTutor.com
Page 19 of 22
What is likely to decrease the accuracy of the experiment?
A Rinsing the flask with acid before each new experiment.
B Stirring the solution throughout each experiment.
C Using the same piece of paper for each experiment.
D Using different measuring cylinders to measure the volumes
of acid and sodium thiosulfate.
ANSWER: A (Don't get this, I thought acid rinsing might make it more reliable? than potentially diluting the acid by rinsing with water)
Q16.
The experiment was repeated at 20 °C using a 250 cm3 conical flask.
Which statement is correct about the time taken for the cross to disappear when
using the larger conical flask?
A The time taken will not be affected by using the larger conical flask.
B The time taken will be decreased by using the larger conical flask.
C The time taken will be increased by using the larger conical flask.
D It is impossible to predict how the time taken will be affected by
using the larger conical flask.
ANSWER = C


Using the larger flask means you have a wider base, so it takes more time to hide the cross as it's more spread out,so it takes more time to block light from reaching the cross, it's harder to explain this but I hope you get it

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