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AQA Chemistry exam question from AS paper 2 2021

06.2. In the second experiment, another flask is used for a combustion reaction.
Method
Remove all the air from the flask.
Add 0.0010 mol of 2,2,4-trimethylpentane (C8H18) to the flask.
Add 0.0200 mol of oxygen to the flask.
Spark the mixture to ensure complete combustion.
Cool the mixture to the original temperature.
The equation is
C8H18(g) + 12 1
2
O2(g) 8 CO2(g) + 9 H2O(l)
Calculate the amount, in moles, of gas in the flask after the reaction.

- I understand how to get 0.0080 moles of CO2 but I am unsure how to get the answer of 0.00155, could someone please explain the reason behind this?

Reply 1

Original post
by Slugzie(:
06.2. In the second experiment, another flask is used for a combustion reaction.
Method
Remove all the air from the flask.
Add 0.0010 mol of 2,2,4-trimethylpentane (C8H18) to the flask.
Add 0.0200 mol of oxygen to the flask.
Spark the mixture to ensure complete combustion.
Cool the mixture to the original temperature.
The equation is
C8H18(g) + 12 1
2
O2(g) 8 CO2(g) + 9 H2O(l)
Calculate the amount, in moles, of gas in the flask after the reaction.
- I understand how to get 0.0080 moles of CO2 but I am unsure how to get the answer of 0.00155, could someone please explain the reason behind this?

You have the balanced equation:
C8H18(g) + 12.5O2(g) 8 CO2(g) + 9 H2O(l)
You are told that there is complete combustion, i.e. the oxygen is in excess.
From the stoichiometry, 0.001 mol of 2,2,4-trimethylpentane will produce 0.008 mol of carbon dioxide (water is a liquid and can be ignored)
The oxygen needed is 0.001 x 12.5 = 0.0125
The available oxygen is 0.02, therefore there is an excess of 0.02 - 0.0125 = 0.0075 mol
Therefore the total mol present after reaction = 0.008 + 0.0075 = 0.0155 mol

Reply 2

Thank you I understand now

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