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Particle is bombarded with electrons which knock off one of the electrons in the particle, forming a 1+ ion
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This is generally used for lower mass particles
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The positive ion is attracted to the negatively charged plate, which accelerates the ion through the field.
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The ion can be broken down further. The fragments are also accelerated and causes different peaks to show on the mass spec (@animazddhdnm @SWAN 2.0 what do peaks mean here? I know what they are mathematically, but I don't know what they are in this sense)
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Used for higher mass substances
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Fragmentation is unlikely to happen - this is called soft ionisation
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Sample dissolved in a substance, which is injected using a hypodermic needle (really thin)
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Needle attached to high voltage power supply, which ionises substance immediately
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X (g) + H+ ---> XH+ (g)
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Solvent evaps and XH+ ions are attracted to negatively charged plate
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This accelerates through mass spec
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1+ ions accelerated using electric field
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All ions accelerated to the same kinetic energy - meaning velocity is dependent on mass
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Ion passes through hole in neg charged plate and move into flight tube
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Time of flight in tube dependent on velocity
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Once they pass through the mass spec, ions hit a negative plate, which causes ionisation of the ion
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The ionisation of the ion causes a current - size proportional to abundance
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Detector plate connected to computer which produces the mass spectrum
Last reply 23 hours ago
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