Limiting reactantsA reaction finishes when one of the reactants is all used up. The other reactant has nothing left to react with, so some of it is left over:
•
the reactant that is all used up is called the limiting reactant
•
the reactant that is left over is described as being in excess
The mass of product formed in a reaction depends upon the mass of the limiting reactant. This is because no more product can form when the limiting reactant is all used up.
Reacting mass calculationsThe maximum mass of product formed in a reaction can be calculated using:
•
the mass of the limiting reactant, and
•
the relative atomic mass (Ar) or relative formula mass (Mr) values of the limiting reactant and the product
Example12 g of magnesium reacts completely with excess hydrochloric acid to form magnesium chloride and hydrogen:
Mg(s) + 2HCl(aq) → MgCl
2(aq) + H
2(g)
Calculate the maximum mass of hydrogen that can be produced. (
Ar of Mg = 24,
Mr of H
2 = 2)
Amount of magnesium =
= 0.5 mol
Looking at the equation, 1 mol of Mg forms 1 mol of H
2, so 0.5 mol of Mg forms 0.5 mol of H
2mass of H
2 =
Mr × amount
= 2 × 0.5
= 1 g
Some examples 1 What mass of hydrogen is formed when 2 g of calcium reacts with hydrochloric acid?
Ca + 2 HCl → CaCl
2 + H
2 2 What mass of carbon dioxide is made when 22 g of propane is burned in oxygen?
C
3H
8 + 5 O
2 → 3 CO
2 + 4 H
2O
3 What mass of iodine is produced when 7.1 g of chlorine reacts with potassium iodide?
Cl
2+ 2 KI → 2 KCl + I
2 4 What mass of aluminium oxide is produced when 135 g of aluminium is burned in oxygen?
4 Al + 3 O
2 → 2 Al
2O
3 5 What mass of magnesium oxide is formed when 6 g of magnesium reacts with oxygen?
2 Mg + O
2 → 2 MgO
6 What mass of carbon dioxide is formed when 2 kg of calcium carbonate reacts with hydrochloric acid?
CaCO
3 + 2 HCl → CaCl
2 + H
2O + CO
2 7 What mass of hydrogen is produced when 195 mg of potassium is added to water?
2 K + 2 H
2O → 2 KOH + H
2 8 What mass of oxygen is needed to react with 4.5 g of ethane (C
2H
6)?
2 C
2H
6 + 7 O
2 → 4 CO
2 + 6 H
2O
9 What mass of oxygen is formed when 735 g of potassium chlorate decomposes?
2 KClO
3 → 2 KCl + 3 O
2