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Chem question help pls

Hi,
Please could I have help on part ii. I know there are two chiral carbons and one double bond so I thought there will be 6 isomers, how did they get 8?
Question: https://ibb.co/3yP94Q6D
Thanks!

Reply 1

Hi, there are 2 chiral carbons which can be arranged in total 4 different ways
++
+-
-+
--
and for each of the 4 arrangements the double bond can be either E or Z 4x2=8
hope this helps

Reply 2

Original post
by sam0273
Hi, there are 2 chiral carbons which can be arranged in total 4 different ways
++
+-
-+
--
and for each of the 4 arrangements the double bond can be either E or Z 4x2=8
hope this helps

ohh, i see, thank you so much!

Reply 3

Original post
by anonymous56754
Hi,
Please could I have help on part ii. I know there are two chiral carbons and one double bond so I thought there will be 6 isomers, how did they get 8?
Question: https://ibb.co/3yP94Q6D
Thanks!

The general rule of thumb is that when you have n stereogenic centres (e.g chiral carbons and asymmetrical alkenes), the maximum number of stereoisomers possible is 2^n.

Since n = 3, there are 2^3 = 8 stereoisomers.

This can be derived from probabilities you did in GCSE/equivalent level maths. The proof likely isn’t needed and I’d say the above explanation is perhaps more likely to be what an examiner would expect.


The proof in case you were interested

Reply 4

Original post
by TypicalNerd
The general rule of thumb is that when you have n stereogenic centres (e.g chiral carbons and asymmetrical alkenes), the maximum number of stereoisomers possible is 2^n.
Since n = 3, there are 2^3 = 8 stereoisomers.
This can be derived from probabilities you did in GCSE/equivalent level maths. The proof likely isn’t needed and I’d say the above explanation is perhaps more likely to be what an examiner would expect.

The proof in case you were interested


Ah I wasn't aware of this, thank you for letting me know! 🙂

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