Here is the question,
A sample of P (C6H1O2) was mixed with an excess of oxygen and the mixture ignited. After cooling to the original temperature, the total volume of gas remaining was 335 cm3. When this gas mixture was passed through aqueous sodium hydroxide, the carbon dioxide reacted and the volume of gas decreased to 155 cm3. Both gas volumes were measured at 25 °C and 105 kPa. Write an equation for the combustion of P in an excess of oxygen and calculate the mass, in mg, of P used. The gas constant R = 8.31 J K−1 mol−1.
I already wrote the equation. I did this calculation and then got an answer which was 2 mg more than what the mark scheme got. I used a different method to the mark scheme:
Mark scheme method - They found the volume of CO2 produced, used pV = nRT to find the moles of carbon dioxide produced and then used this to find the mass of P produced
My method - I used the total volume in the pV = nRT, worked out the molar ratio of CO2 and O2 from the balanced chemical equation, and then used this to find the mole of carbon dioxide produced, and then used this to find the mass of P produced.
Is my method wrong? I have used it before and it has worked out fine but I'm not sure why it does not work in this case.
Any help would be appreciated!