I would copy the extracurricular activities, research programs, STEM challenges, and club positions of people admitted to MIT and Harvard. A student might choose a major on the application, then change majors after they start university. Harvard students wrote their personal essays about learning resilience by overcoming a challenge or negotiating with someone, for example one's parents, to get what s/he wants. It seems that Harvard values these topics. I am not sure. I think Harvard values letters of recommendations from high status people, such as partners of prestigious firms, celebrities, government officials, or politicians. Harvard accepts people from feeder schools.
Someone from England applied to MIT and was rejected. She had high grades, but little to no extracurricular activities. It seems that MIT values extracurricular activities along with grades.
To prepare for A-levels, I would read the top band of the mark scheme and do what is needed for top marks, for example doing past papers with a timer.
I don't know if you would benefit from the memory technique spaced repetition during the years of A-levels.
To prepare for STEM challenges, I'd look at the questions and solutions.