As Worzo said, a radian is the angle where a piece od the circle has the same length on all sides (2 lots of the radius, and a radius length for the arc). The theory behind it is that it is a measure of the angle of an arc, with respect to the length of the curve and the radius of the circle.
I find the best was to remember the figures involved is that the formula for the circumference is 2pi(r). So there are 2pi radians in a circle.