Repulsive interactions are often related to electrostatics. You know that positive and positive charges repel, and negative and negative charges repel. Attractive forces occur between something positively charged (e.g. nucleus) and something negatively charged (e.g. electrons).
One example of repulsive molecular/atomic interactions is that two atomic nuclei can never come very close to each other, due to the repulsion between like positive charges. (This is one of the obstacles to making fusion feasible on a large scale). Or else, two positive ions won't attract each other - they'll repel.
I hope this helps!
Edit - also, yep! Hydrophobic interactions are between non-polar hydrophobes and water.
Wait so Hydrophobic interactions are between non-polar hydrophobes and water not non-polar hydrophobes and non-polar hydrophobes ?