Na/Nb is proportional to Zab which is collision number/density. It says it in the slide show?
Does this question make any sense to you?
i) The collision diameters of NO and Cl2 are 370 x 10-12 m and 540 x 10-12 m, respectively. Taking the relative molecular masses as 30 amu and 70 amu, use the hard-sphere collision theory to estimate the rate constant at 300 K for the gas-phase reaction: NO + Cl2 → NOCl + Cl Express k in dm3 mol-1 s-1 indicating clearly any other assumptions made (1 amu = 1.66 x 10-27 kg).