In an electrochemical cell what is the purpose of the salt bridge. I know the definition by heart,"to complete the circuit and allow movement of ions", but I don't understand why ions need to move from one half cell to another when all that's needed for reduction and oxidation to occur is the movement of electrons which is already dealt with by an external circuit. I'm so confused someone please clarify
In an electrochemical cell what is the purpose of the salt bridge. I know the definition by heart,"to complete the circuit and allow movement of ions", but I don't understand why ions need to move from one half cell to another when all that's needed for reduction and oxidation to occur is the movement of electrons which is already dealt with by an external circuit. I'm so confused someone please clarify
Just the external circuit doesn't mean the circuit is closed.
Take two beakers, put some chemicals in each, put a copper wire into both solutions. You don't have a closed circuit - closed circuit means a loop, there is no loop yet.
The salt bridge does complete the circuit and allows the current to flow, but it also maintains the concentration of the solution by replenishing or taking out excess concentration (cant think of the right word there haha sorry)