First equation more positive, so spontaneous (forward). The second equation will go backward, and electrons cancel:
S2O8(2-) + 2Ag ---> 2SO4(2-) + 2Ag+
Emf = 2.01 - 0.8 = 1.21 V
PART (II)
Increase in SO4(2-) shifts the equilbrium to the left - backwards. So the electrode potential should decrease.
thanks a lot . So the reaction which is less positive always goes backwards? and hence this is the way to work out the half equation and thus the full ionic equations?
thanks a lot . So the reaction which is less positive always goes backwards? and hence this is the way to work out the half equation and thus the full ionic equations?