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pH and buffers help!

I'm a med student and finding the following two questions a little tricky, any help would be much appreciated :smile:
1) Write down your prediction of the structure of the predominant ionic species of the dipeptide aspartyl cysteine at each of the following pH values : 1,5,7,9,11 2) What causes the pKa for the side chain of histidine residues in a protein to differ from the value of the simple amino acid (referring to haemoglobin)

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