When we talk about AD we are talking about the whole economy, and therefore the kind of thing you're suggesting doesn't really apply. What it is important to recognise is the extent to which a rise (or fall) in AD affects unemployment is variable and depends on the level of spare capacity in the economy - after the 2008/9 recession purely from the fall in AD you would have expected UK unemployment to be signifiantly higher than it actually was because instead of making workers unemployed companies cut their hours increasing the slack in the economy. When the economy picked up again this meant AD could initially increase with little increase in employment - because there was plenty of spare capacity in the people that were already employed. Obviously if the increase in AD is mainly down to growth in industries which are not very labour intensive then you will see a smaller rise in employment than you would otherwise, but either way aggregate demand and unemployment rates are negatively correlated.
I do see what you're getting at but consider it this way say one sector of the economy lowers prices because of an investment in capitol which lowers its unit costs some of the money that people save will go on to be spent in other areas of the economy which are labour intensive like service industries which will have to employ more people to cope with the increased demand. Because the whole of the economy is linked you couldn't have an increase in AD solely caused by capitol intensive production methods being used.