PV = nRT
Pressure in Pa, Volume in m^3
1atm = 101000 Pa
cm^3 x 10^-6 -> m^3
For ethanol, n = (101000 x 50 x 10^-6)/8.314 x 400 = 0.0015 moles
For oxygen, n = (101000 x 200 x 10^-6)/8.314 x 400 = 0.006 moles
0.0015 moles ethanol needs 0.0045 moles oxygen, but have 0.006 moles oxygen, oxygen in excess
ethanol + 3 oxygen -> 2 carbon dioxide + 3 water
initial: 0.0015, 0.006, _, _
change: -0.0015, -0.0045, +0.0030, +0.0045
final: 0, 0.0015, 0.0030, 0.0045
total moles = 0.009 moles
Volume = (0.009 x 8.314 x 400)/101000 = (2.963 x 10^-4)m^3 x 10^6 = 296 cm3 = 300 cm3
As it is a multiple choice question, Im sure there is a faster way
Here is the faster way
https://www.thestudentroom.co.uk/showthread.php?t=7012791‘For ethanol and O2 to react in a 1:3 ratio (as in the equation), 150cm3 of O2 will be used - leaving 50cm3 unreacted because it is in excess.
The products will take up 250 cm3 - (50cm3 of ethanol x 5), but the question asks for the total volume of gas, not just the volume of products, so there will be 300 cm3 in total.
Hope this helps lol’