On the welsh radio a couple of nights ago it was mentioned that higher than normal silicone levels had been detected in some of the fuel from affected cars. The increased level of silicone has coated the oxygen sensor and has therefore mucked up the ECU.
Methyl Silicone is used as an anti-foam additive in oil. It's normally around 10-15ppm of Si measured in elemental analysis, but this can also be a measure of the dust entering the oil. Too much and it actively encourages foaming.
Organic Silicon compounds (siloxanes) are used as anti-foaming agents in oils and detergents, but I can't see why anyone would put them into petrol.
Certainly in fuels such as 'bio-gas' the presence of organic silicon causes major problems and is seen as a contaminant that causes damage to Combined Heat and Power (CHP) engines.
When burnt these compounds are oxidised into silicon di-oxide (silica, the major component of sand). In a conventional 4-stroke motor this silicon oxide would deposit at the spark plugs, valves, and valve guides, causing abrasion and, eventually, serious damage - it would be akin to leaving valve grinding paste in your engine.
I would also think it highly likely that if siloxane contamination was present in this case then it would also cause deposition in other hot areas such as the catalyst and it's associated lambda (oxygen) sensor(s) hence the ECU faults reported on the radio?
What I suspect happened was that a tanker that had previosly carried silicon based chemicals, was filled with however many million gallons of petrol they carry without being properly cleaned out. The fuel became contaminated.