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What are Van der Waals forces?!

Somebody has said that they are the sum of the attractive and repulsive forces, yet elsewhere I've heard that they are the same as instantaneous dipole-induced dipole bonds?

Thanks in advance
Reply 1
Van der Waals forces include all attractive and repulsive forces between molecules. Except those forces which are due to covalent bonds or electrostatic interaction of ions. This includes instantaneous dipole-induced dipole. :smile:
Original post by SaFa1237
Van der Waals forces include all attractive and repulsive forces between molecules. Except those forces which are due to covalent bonds or electrostatic interaction of ions. This includes instantaneous dipole-induced dipole. :smile:


I believe that permanent dipole-dipole interactions such as hydrogen bonds are also excluded from the definition of Van der Waal's forces.
Reply 3
Original post by gingernat
Somebody has said that they are the sum of the attractive and repulsive forces, yet elsewhere I've heard that they are the same as instantaneous dipole-induced dipole bonds?

Thanks in advance


They're intermolecular forces
How theyre formed: movement of electrons causes an instantaneous dipole
This dipole induces neighbouring dipoles
They all gain small forces of attraction
Van der waals



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Original post by gingernat
Somebody has said that they are the sum of the attractive and repulsive forces, yet elsewhere I've heard that they are the same as instantaneous dipole-induced dipole bonds?

Thanks in advance


What Sa-Fa and Chemist Boy said. Van der Waals are also known as London forces
What people have said above but note that they are very weak IMFs.
http://goldbook.iupac.org/V06597.html

The confusion comes from A-level texts/exams that use VdW forces to mean only instantaneous dipole-induced dipoles. Not overly helpful, really.

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