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AQA A Level Chemistry Paper 2 11th June Unofficial Markscheme

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Original post by ÷by0
i think you already know mr = 118, you know it has 2 -COOH groups. It is not branched.

Mass COOH = 12 + 32 + 1 = 45
x2 = 90
Mr - 90 = 28
there must be CH2 in between groups, CH2 has mass 14.
28/14 = 2
=> HOOCCH2CH2COOH

Please rep if this was helpful !

was that the structure of A or B
ps i repped you too many times its not letting me rep you again
Reply 121
That is the structure of the Carboxylic acid, not a or b.
Original post by jamesctu
was that the structure of A or B
ps i repped you too many times its not letting me rep you again
what about the question that said the molecular formula was the same as the empirical formula- how was that worked out ? 😣
Original post by ÷by0
That is the structure of the Carboxylic acid, not a or b.


Compounds C and D both have the molecular formula c6h3Br3
C has two peaks in its 13C NMR spectrum
D has four peaks in its c13 NMR spectrum
C
D
this is the second part how would you calculate this
@÷by0
(edited 4 years ago)
Reply 124
that was just telling you, because if it was different then you would have to find and empirical mass, and then multiply it all by some integer. For example, empirical formula might be C2H5, but Mr = 58. So you world have to say if empirical mass = 29, then 2x empirical mass = molecular mass
Therefore 2x empirical formula = molecular formula = C4H10 - butane.
But in that question, em=Mr, so you didn't have to worry about that. :smile:
Original post by naimahh14
what about the question that said the molecular formula was the same as the empirical formula- how was that worked out ? 😣
Compounds C and D both have the molecular formula c6h3Br3
C has two peaks in its 13C NMR spectrum
D has four peaks in its c13 NMR spectrum
C
D
this is the second part how would you calculate this
Original post by ÷by0
that was just telling you, because if it was different then you would have to find and empirical mass, and then multiply it all by some integer. For example, empirical formula might be C2H5, but Mr = 58. So you world have to say if empirical mass = 29, then 2x empirical mass = molecular mass
Therefore 2x empirical formula = molecular formula = C4H10 - butane.
But in that question, em=Mr, so you didn't have to worry about that. :smile:
Reply 126
How do you calculate the structure of C and D?
Original post by jamesctu
Compounds C and D both have the molecular formula c6h3Br3
C has two peaks in its 13C NMR spectrum
D has four peaks in its c13 NMR spectrum
C
D
this is the second part how would you calculate this
Original post by ÷by0
How do you calculate the structure of C and D?

this is q7
i have no clue on this
Reply 128
which one or both? i can add that answer to my solution bank next?
Original post by jamesctu
this is q7
i have no clue on this
Original post by ÷by0
which one or both? i can add that answer to my solution bank next?

what i attatched previously is only question 7
7 part 1
and 7 part 2
Reply 130
@jamesctu ok i will answer those next on the solution bank
what does that mean
Original post by ÷by0
@jamesctu ok i will answer those next on the solution bank
Reply 132
Original post by jamesctu
what does that mean

i have created a thread where i am position a full "solution bank" of the paper to organise all the answers on the unofficial mark scheme.
Paper 2 solutions
Reply 133
@Evilhomer chemistry solution bank in the making
What do you reckon the grade boundaries will be for a B?
The question with ethanoic anhydride formed an ester and a carboxylix acid if i remember correctly.
Original post by solidcashmoney
The question with ethanoic anhydride formed an ester and a carboxylix acid if i remember correctly.

hi can you please help
do you know how to answer these
Original post by blueoreo
Any1 got predictions for the gradeboundaries? I got As on the 2017/2018 papers but feel like I'll get a B on these ones. ;c


Same here that paper was awful 😕
Original post by skills0786
Guys, what is the Z,Z Question??? Like I dont recall it...what were the other sub Questions relating to it?? Just so that I can figure out if I actually saw that Q or missed it out... :frown:

It was a big horrible skeletal stucture that was partly drawn out, and you had to finish it. Think it was only 1 mark and I don't remember any sub questions
You would, cytosine is the nitrogenous base, cytosine, pentose sugar and phosphate makes up the nucleotide!!
Original post by friendjm
A nucleotide is only cytosine you wouldn't circle deoxyribose sugar or the phosphate
(edited 4 years ago)

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