I have a solution of 3 compounds, 4-nitrobenzoic acid, ethyl 4-nitrobenzenoate and ethyl 4-aminobenzoate. ( I need to isolate the ethyl 4-nitrobenzoate and ethyl 4-aminobenzoate)
I'm going to be using a separating funnel to separate the compounds and have a few solvents and solutions I can use
Diethyl ether
Dichloromethane
Water
NaOH (aq)
HCl (aq)
Saturated NaHCO3
Saturated NaCl
I was going to use DCM as the organic layer and NaOH(aq) as the aqueous layer as the 4-nitrobenzoic acid will dissolve in this dissolve in this, then I can run the aqueous layer off (and repeat?) and I will be left with the 2 compounds I need, then I could add HCl(?) to seperate the two, ethyl 4-nitrobenzoate will be in the organic layer and ethyl 4-aminobenzoate in the aquous. Then i'm not sure if I would need to add anything to do the ethyl 4-aminobenzoate to remove the hydrogen ion or not.
Does this sound ok? i'm also not sure as to the difference between using diethyl ether and DCM, and NaOH or NaHCO3