The Student Room Group

urgent chemistry help

A sample of titanium contains four isotopes, 46Ti, 47Ti, 48Ti and 49Ti
This sample has a relative atomic mass of 47.8
In this sample the ratio of abundance of isotopes 46Ti, 47Ti and 49Ti is 2:2:1
Calculate the percentage abundance of 46Ti in this sample.


the mark scheme states to use 49 as x
and to do (48 x (100 - 5x) ) as part of the formula.

where did the 100 and 5 come from and why are we using specifically the 49 as x???
Reply 1
The 5 comes from the total ratio of the abundances you are given. (2+2+1 = 5). It would be most efficient to suppose that the abundance of Ti49 is x, because this is equal to 1. Therefore, the abundance of Ti46 and Ti47 are both equal to 2x.
The 100 comes from expressing abundance as a percentage, as the question is asking for percentage abundance. If 100 is the total abundance, then the abundance of Ti48 would be 48 lots of (100 - 5x). 48 is the relative atomic mass of the titanium isotope, 100 is the total abundance as a percentage, minus 5x which is the total abundance of the other Ti isotopes.

Therefore: (46 x 2x) + (47 x 2x) + (48(100-5x)) + (49 x 1x) / 100 = 47.8.
92x + 94x + 48 (100-5x) + 49x = 4780
235x + 4800 - 240x = 4780
-5x = -20
x = 4.
If x = 4%, then the abundance of Ti46 in the sample is 2x which = 8%,

If you wanted to make the abundance of Ti46 and Ti47 = x,
Then 46x + 47x + 48(100 - 2.5x) + (49 x 0.5x) / 100 = 47.8
93x + 4800 - 120x + 24.5x = 4780
-2.5x + 4800 = 4780
-2.5x = -20,
Therefore x = 8% which is the answer.
(edited 11 months ago)
Reply 2
Original post by Ðeggs
The 5 comes from the total ratio of the abundances you are given. (2+2+1 = 5). It would be most efficient to suppose that the abundance of Ti49 is x, because this is equal to 1. Therefore, the abundance of Ti46 and Ti47 are both equal to 2x.
The 100 comes from expressing abundance as a percentage, as the question is asking for percentage abundance. If 100 is the total abundance, then the abundance of Ti48 would be 48 lots of (100 - 5x). 48 is the relative atomic mass of the titanium isotope, 100 is the total abundance as a percentage, minus 5x which is the total abundance of the other Ti isotopes.

Therefore: (46 x 2x) + (47 x 2x) + (48(100-5x)) + (49 x 1x) / 100 = 47.8.
92x + 94x + 48 (100-5x) + 49x = 4780
235x + 4800 - 240x = 4780
-5x = -20
x = 4.
If x = 4%, then the abundance of Ti46 in the sample is 2x which = 8%,

If you wanted to make the abundance of Ti46 and Ti47 = x,
Then 46x + 47x + 48(100 - 2.5x) + (49 x 0.5x) / 100 = 47.8
93x + 4800 - 120x + 24.5x = 4780
-2.5x + 4800 = 4780
-2.5x = -20,
Therefore x = 8% which is the answer.

thank you so much!!!!

Quick Reply

Latest