(b) is probably slightly less easier than (a) and also better to demonstrate what you should be doing.
Equality of sets is intimately related to their extension, viz. two sets are determined equal when they have the same elements. If A is a subset of B then every element of A is an element of B and if B is a subset of A then every element of B is an element of A whence A and B are equal.
It is not too difficult to show that if A = B then A is a subset of B and B is a subset of A.
So for (a) you need to prove that LHS is a subset of the RHS and conversely the RHS is a subset of the LHS.
(b);
Let x be an element of (PxQ) u (RxS). It follows that x is either an element of PxQ or RxS (or both), hence x = (p,q) or x = (r,s) for some p in P, q in Q or r in R and s in S (or potentially both, but once again this doesn't really matter because if an element is in both it is in one so we can deal with it then).
If x = (p,q) then the first coordinate is an element of P and the second coordinate is an element of Q. Hence the first coordinate is an element of P or R (potentially adding things is just making our set even bigger!) and similarly q is an element of Q or S whence x is a subset of (P u R) x (Q u S).
If x = (r,s) then the first coordinate is an element of R and the second coordinate is an element of S. Hence the first coordinate is an element of P or R (potentially adding things is just making our set even bigger!) and similarly q is an element of Q or S whence x is a subset of (P u R) x (Q u S).
I hope this has aided you and also showed you why we have inclusion - consider the effect of an element in R but not P and in S but not Q - will this be an element of (P x Q) u (R x S) ?