I would start by sketching a diagram to show the path of the waves which travel 120km directly and those which reflect off the ionosphere. Assume that the point of reflection is exactly half way along the 120km. You should then be able to use Pythagoras to work out exactly how far these reflected waves travel.
Now you can find the path difference between the reflected waves and those which travel directly along the surface. And then, of course, you need to know whether that path difference is a whole number multiple of the wavelength or not to work out the phase difference.
Normally of course, a path diff of a whole nº of wavelengths means waves arriving in phase and a diff of (n + 1/2) means antiphase. BUT there's a twist here, as we are told that the reflection produces a phase change of 180º.
So, do the waves meet in phase, or not...?
If you need more details help let me know but have a go first using the above.