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AS Level Chemistry Help

Please help me understan what i am supposed to do here...

Given that

P(g) + 3Cl(g) = PCl3(g) energy change = -983kjmol-1
P(s) + 3/2Cl2(g) = PCl3(g) energy change = -305kjmol-1
P(s) = P(g) energy change = +314kjmol-1

calculate the following bond energies:

a) P-Cl in PCl3

b) Cl-Cl in Cl2

i really have absolutley no idea what to do so some help would be much appreciated :smile:

Original post by Aleisha1
Please help me understan what i am supposed to do here...

Given that

P(g) + 3Cl(g) = PCl3(g) energy change = -983kjmol-1
P(s) + 3/2Cl2(g) = PCl3(g) energy change = -305kjmol-1
P(s) = P(g) energy change = +314kjmol-1

calculate the following bond energies:

a) P-Cl in PCl3

b) Cl-Cl in Cl2

i really have absolutley no idea what to do so some help would be much appreciated :smile:



a) Look at the first equation and consider the definition of bond energy ...
Reply 2
Original post by charco
a) Look at the first equation and consider the definition of bond energy ...


Hi sorry i still dont understand. i have nothing in my notes or text book telling me how to do this so i am basically starting from scratch :s
Original post by Aleisha1
Hi sorry i still dont understand. i have nothing in my notes or text book telling me how to do this so i am basically starting from scratch :s


The bond energy is the energy required to break 1 mole of specific bonds giving gaseous atoms.

Look again at the first equation and ask yourself "what is happening to get from reactant to products?" ...
Reply 4
Original post by Aleisha1
Please help me understan what i am supposed to do here...

Given that

P(g) + 3Cl(g) = PCl3(g) energy change = -983kjmol-1
P(s) + 3/2Cl2(g) = PCl3(g) energy change = -305kjmol-1
P(s) = P(g) energy change = +314kjmol-1

calculate the following bond energies:

a) P-Cl in PCl3

b) Cl-Cl in Cl2

i really have absolutley no idea what to do so some help would be much appreciated :smile:



What bonds (notice plural) are you forming in reaction one ? How much energy is being released to form these ? Therefore how much energy would be required to BREAK one of them ?
Bond enthalpies are always quoted as positive as the definition is to break bonds.
Question b you'll need to piece together reactions 2 and 3.
Reply 5
Original post by charco
The bond energy is the energy required to break 1 mole of specific bonds giving gaseous atoms.

Look again at the first equation and ask yourself "what is happening to get from reactant to products?" ...


thanks i think i get it now :smile:
Reply 6
Original post by Spoogle
What bonds (notice plural) are you forming in reaction one ? How much energy is being released to form these ? Therefore how much energy would be required to BREAK one of them ?
Bond enthalpies are always quoted as positive as the definition is to break bonds.
Question b you'll need to piece together reactions 2 and 3.


thankyou very much very helpful :smile:

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