Be very careful here; note that the question is asking for number of molecules.
Necessary prerequisite information:
The mole ([mol.]) is a unit referring to (6.02 [...])(1023) elementary entities (molecules, ions, atoms, etc.).
Given information:
Mass (sample): 200 [mg], ≡ (200)(10-3) [g]
Diazepam formula: C16H13ClN2O
Calculations:
Molar Mass: (12)(16) + (1)(13) + (35.5) + (14)(2) + (16) = 284.5 [g][mol]-1
∵
Moles [mol.] = (Mass [g])(Molar Mass [g][mol.]-1)-1,
Moles [mol.] = ((200)(10- 3) [g])(284.5 [g][mol.]-1)-1 = (7.02)(10-4) [mol.]
∵
One mole [mol.] = (6.02 [...])(1023) molecules,
(7.02)(10-4) moles [mol.] = (7.02)(10-4)(6.02 [...])(1023) = (4.23)(1020) molecules = (4.2)(1020) molecules, to one decimal place.