You can see the ratio of reactants given in the equation; 1 mol O2 gives 2 mol CaO.
So try multiplying up everything by 2 (as you’re given 2 mols O2 to react), which gives 4Ca 2O2 —> 4CaO. As you’ve used all your moles of O2, O2 is the limiting reagent. And you can see how much product from the equation.
You can verify that O2 is the limiting reagent by multiplying up the equation by 5, to use all of the Ca given. This is: 10Ca 5O2 —> 10CaO. You can see that you’re using more moles of O2 than you have, so O2 must be the limiting reagent.