It doesn't matter which you take as your third option for any medical school except Cambridge. All other medical schools have no preference what your third option is. You could well take art, Latin, or geography and they would all be seen as the same, provided you get the same grade in the end (you really need an A or A* in whatever your third subject is). So any of the three you listed are fine.
I would however make a general observation that politics, sociology, and psychology are not humanities subjects, they are social sciences.