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You need to contact the exam officer of the exam centre to book your exams
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You need to do this by Februrary at the latest to avoid late fees and by April should you avoid missing out of doing the exams this year
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Bookings are usually available from Novermber in each academic year, but I think Tutors & Exams are flexible with this
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You would need to pay for admin and exam fees for the GCSE (which I think is about £100 if memory serves - this includes the £49.30 exam fee, but not the admin fee; see: https://qualifications.pearson.com/content/dam/pdf/Support/Fees-for-academic-and-vocational-qualifications/uk-general-qualifications-fees-2023-24.pdf). The fees are payable to the exam centre, not the exam board.
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You would need a copy of your ID to make your submission, but this can be done by email (make sure it's secure)