Mm, Sciences Po is pretty well known within Europe generally (including in the UK). However all of them are - perhaps KU Leuven a little less outside of academia, but even still. As above though it depends somewhat on your plans for the degree; if you want to go into academia, "prestige" of the university is noting compared to that of your thesis supervisor(s) and the individual department(s) involved...
For going into e.g. business generally then, "prestige" is I suppose all that matters typically. They're all fine, as above KU Leuven may be a little less well known outside of Belgium in business (although very Euro-centric or international businesses may be more familiar with it anyway). The UK ones I imagine are reasonably well known/regarded, and Sciences Po will be known. In France itself for business I would imagine HEC/X/Ulm are probably the biggest names but Sciences Po isn't too far behind as I understand?
As for working in politics and international relations then...I can't really say unfortunately, as I'm not really that familiar with the area. My impression is this often necessitates getting a PhD anyway so, the academia recommendations above may be relevant?