I think we're both looking at totally different forms here. On mine, section 4 is previous licence details, section 5 is health, section 6 is confirming your identity. Maybe there's a brand spanking new version out that I don't have here.
But I can see a bit about serial numbers now under section 6 part B so I think I understand. Part B is for if you don't have a digital passport or choose to send in your documents rather than simply asking them to check your identity with the passport office. Under the circumstances, the serial number will be the passport number (if this is the document you choose to send).
Of course, if you do have a digital passport, just enter your 9 digit passport number in Part A and sign it, then you don't need to fill in Part B at all or actually send the passport.