Only person I knew who sucessfully went into a decent (actually very decent..) job in a well known NGO straight from uni did it by gaining a ton of contacts, references and experiance..
She never did any paid work whilst at university (had jobs before though)
But instead she started with unpaid internships (competative in their own right) and worked her way up to more well-kown charitable/campaigning organisations, each time picking up a very positive reference, and trying to vary her position (so not always working in the same role for each organisation)
Dont get me wrong, at the time she hated it. long hours, lots of work, no pay, and all on top of her uni work..
But it paid off.. she graduated with a wealth of experiance, a lot of conifidence, and some brilliant references and connections.. In the end it was one of her previous bosses, who tipped her off and pointed her in the dirrection of her current job. which she didnt struggle to get, as it was no problem proving she could do the work, when well.. she had been doing it for the past 2 years.
It seemed to me like one hell of a slog, but it certianly paid off.. and compared to graduates with just a degree, she was hugely employable..
- Not sure if that helps.. im sure there are many ways into your typical NGO type organisations.. thats just the only person ive known to go into one right from uni..